Cu元素为29号元素,原子核外有29个电子,核外电子排布式为:1s22s22p63s23p63d104s1,与铜同周期、基态原子最外层电子数相同的核外电子排布式为:1s22s22p63s23p63d54s1或[Ar]3d54s1,故答案为:1s22s22p63s23p63d54s1或[Ar]3d54s1.