a、因为0.090≠0.009,所以数值不相等,不合题意;b、0.009≠0.09,所以数值不相等,不合题意;c、0.090=0.09,0.090的计数单位是0.001,0.09的计数单位是0.01,所以数值相等而计数单位不同;故选:c.