加入氯化铵就形成缓冲溶液了,PH=14-pKb+lg[NH3.H2O]/[NH4Cl]=14-4.75+lg(0.1/[NH4Cl])=9,所以lg(0.1/[NH4Cl])=-0.25=lg0.1-lg[NH4Cl],所以lg[NH4Cl]=-0.75,则[NH4Cl]=1/5.62mol/L,所以m=Mn=53.5×1×1/5.62≈9.52g